Ionic radii and radius ratio

Ionic radii refers to the size of an ion, which is typically smaller than the size of the corresponding neutral atom due to the gain or loss of one or more electrons. The ionic radius of an ion can be determined by measuring the distance between the nuclei of two ions that are bonded together.…

Packing in fcc, bcc and hcp lattices

The three most common crystal structures are face-centered cubic (FCC), body-centered cubic (BCC), and hexagonal close-packed (HCP) lattices. The packing in each of these structures is as follows: In terms of packing efficiency, FCC and HCP lattices are more efficient than the BCC lattice. This is because in the FCC and HCP lattices, the atoms…

Seven crystal systems (cell parameters a, b, c, α, β, γ)

The seven crystal systems and their corresponding cell parameters are: In each crystal system, the cell parameters describe the dimensions and angles of the unit cell, which is the basic repeating unit of a crystal lattice. The dimensions are given by the three lengths a, b, and c, and the angles between them, α, β,…

Crystalline state

The crystalline state is a state of matter in which the constituent particles, such as atoms, molecules, or ions, are arranged in a highly ordered, repeating three-dimensional pattern called a crystal lattice. In this state, the particles are held together by strong intermolecular forces and exhibit a characteristic set of physical and chemical properties, such…

Enzyme catalysis and Its mechanism

Enzymes are biological catalysts that speed up the rate of chemical reactions in living organisms. Enzymes are highly specific, meaning that they catalyze only one or a few types of chemical reactions. The mechanism by which enzymes catalyze chemical reactions is through a process called enzyme catalysis. Enzyme catalysis involves several steps: The mechanism by…

Catalysis : Homogeneous and heterogeneous

Catalysis refers to the process in which a catalyst increases the rate of a chemical reaction by providing an alternative pathway with lower activation energy. There are two types of catalysis: homogeneous catalysis and heterogeneous catalysis. Homogeneous catalysis involves a catalyst that is in the same phase (i.e., gas, liquid, or solid) as the reactants.…

Temperature dependence of rate constant (Arrhenius equation and activation energy)

The temperature dependence of a chemical reaction’s rate constant can be described by the Arrhenius equation, which relates the rate constant to the temperature and the activation energy of the reaction: k = A * exp(-Ea/RT) where k is the rate constant, A is the pre-exponential factor or frequency factor, Ea is the activation energy,…

Differential and integrated rate expressions for zero and first order reactions

The rate of a chemical reaction is the change in the concentration of reactants or products per unit time. The rate law for a chemical reaction describes how the rate of the reaction depends on the concentrations of the reactants. There are different rate laws for different types of reactions, but two common types are…

Rate constant

The rate constant, also known as the reaction rate constant, is a proportionality constant that relates the rate of a chemical reaction to the concentrations of the reactants. It is typically denoted by the symbol k and has units of inverse time (e.g., s^-1, min^-1, etc.). The value of the rate constant depends on a…

Batteries : Primary and Secondary

Batteries are devices that convert stored chemical energy into electrical energy. There are two main types of batteries: primary and secondary. Primary batteries are non-rechargeable batteries that are designed to be used once and then discarded. They are commonly used in low-drain devices such as flashlights, remote controls, and smoke detectors. Primary batteries have a…