Enthalpy of reaction

The enthalpy of reaction (ΔHrxn) is the amount of heat released or absorbed during a chemical reaction at a constant pressure. It represents the change in the enthalpy of the system as reactants are transformed into products. If the enthalpy of reaction is negative (ΔHrxn < 0), it means that the reaction is exothermic, and…

Hess’s law

Hess’s law is a fundamental principle in chemistry that states that the total enthalpy change of a chemical reaction is independent of the pathway between the initial and final states. In other words, if a reaction can occur by multiple paths, the change in enthalpy will be the same regardless of the specific path taken.…

Enthalpy

Enthalpy (H) is a thermodynamic property that describes the total heat content of a system at constant pressure. It is defined as the sum of the internal energy (U) of the system and the product of the pressure (P) and volume (V) of the system: H = U + PV Enthalpy is a state function,…

Internal energy

Internal energy refers to the total energy that is contained within a system. This energy includes the kinetic and potential energies of the particles within the system, as well as any other forms of energy that may be present, such as chemical energy, thermal energy, and nuclear energy. The internal energy of a system is…

First law of thermodynamics

The first law of thermodynamics, also known as the law of conservation of energy, states that energy cannot be created or destroyed, only transformed from one form to another or transferred from one system to another. In other words, the total amount of energy in a closed system remains constant. This law is fundamental to…

State Functions

In thermodynamics, a state function is a property of a system that depends only on the current state or condition of the system and not on how the system arrived at that state. State functions are also known as state variables or state quantities. Some common examples of state functions include: State functions are extremely…

Intensive and Extensive properties

In thermodynamics, properties of matter can be classified as either intensive or extensive. Intensive properties are properties that do not depend on the amount of matter present. Examples of intensive properties include temperature, pressure, density, and specific heat capacity. These properties are useful in describing the state of a system and can be used to…

Tetrahedral and Octahedral

Tetrahedral and octahedral are two geometric shapes commonly found in chemistry and crystallography. Tetrahedral refers to a shape with four sides, each of which is a triangle. The tetrahedron is a regular solid with four identical equilateral triangles as its faces, and it is often used to describe the molecular geometry of compounds with four…

Trigonal bipyramidal

Trigonal bipyramidal is a term used in chemistry to describe the shape of molecules that have five atoms or groups of atoms bonded to a central atom. The shape is named trigonal bipyramidal because it has three equatorial atoms in a plane that form an equilateral triangle, and two axial atoms above and below this…

Square planar

Square planar refers to the geometry or arrangement of atoms or ligands around a central atom in a molecule or ion, where the central atom is located at the center of a square plane. In a square planar arrangement, the central atom is surrounded by four ligands or atoms that are arranged in a flat,…