Second law of thermodynamics

The second law of thermodynamics is a fundamental principle in physics that states that in any spontaneous process, the total entropy of a closed system will always increase over time, or remain constant in ideal cases. Entropy is a measure of the disorder or randomness of a system, and the second law of thermodynamics tells…

Hess’s law

Hess’s law is a fundamental principle in chemistry that states that the total enthalpy change of a chemical reaction is independent of the pathway between the initial and final states. In other words, if a reaction can occur by multiple paths, the change in enthalpy will be the same regardless of the specific path taken.…

Intensive and Extensive properties

In thermodynamics, properties of matter can be classified as either intensive or extensive. Intensive properties are properties that do not depend on the amount of matter present. Examples of intensive properties include temperature, pressure, density, and specific heat capacity. These properties are useful in describing the state of a system and can be used to…

Tetrahedral and Octahedral

Tetrahedral and octahedral are two geometric shapes commonly found in chemistry and crystallography. Tetrahedral refers to a shape with four sides, each of which is a triangle. The tetrahedron is a regular solid with four identical equilateral triangles as its faces, and it is often used to describe the molecular geometry of compounds with four…

Molecular orbital energy diagrams for homonuclear diatomic species (up to Ne2)

Sure, here are the molecular orbital energy diagrams for homonuclear diatomic species from H2 to Ne2: 1.H2 sigma(2s) *sigma*(2s) *sigma(2p)pi(2p) *pi*(2p) * 2.He2 sigma(1s) *sigma*(1s) * 3.Li2 sigma(1s) *sigma*(1s) *sigma(2s)pi(2p) *pi*(2p) * 4.Be2 sigma(1s) *sigma*(1s) *sigma(2s)sigma(2p) *pi(2p) *pi*(2p) * 5.B2 sigma(1s) *sigma*(1s) *sigma(2s)sigma(2p) *pi(2p) *pi*(2p) * 6.C2 sigma(1s) *sigma*(1s) *sigma(2s)pi(2p) *pi*(2p) *sigma(2p) * 7.N2 sigma(1s)…

Hybridisation involving s, p and d orbitals only

Hybridization is a concept in chemistry where atomic orbitals combine to form hybrid orbitals that have different shapes and energies from the original atomic orbitals. The most common types of hybridization involve s and p orbitals, but d orbitals can also be involved in certain cases. Hybridization involving only s, p, and d orbitals is…

Aufbau Principle

The Aufbau principle, also known as the Aufbau rule, is a fundamental concept in chemistry that explains the order in which electrons fill atomic orbitals in an atom. It is based on the idea that electrons occupy the lowest available energy level or orbital first, before filling higher levels or orbitals. According to the Aufbau…

Shapes of s, p and d orbitals

The shapes of s, p, and d orbitals are as follows: It’s important to note that the shapes of these orbitals are theoretical representations based on mathematical models, and the actual distribution of electrons in an atom is more complex and dynamic. What is Required Shapes of s, p and d orbitals The shapes of…

Uncertainty principle

The uncertainty principle is a fundamental principle of quantum mechanics, which states that certain pairs of physical properties of a particle, such as position and momentum, cannot both be precisely determined or known simultaneously. This means that the more accurately we know the position of a particle, the less precisely we can know its momentum,…

Viscosity

Viscosity is a measure of a fluid’s resistance to flow. In simpler terms, it is the internal friction between different layers of fluid as they move past each other. Viscosity is commonly measured in units of poise or centipoise, and is dependent on factors such as temperature, pressure, and composition of the fluid. Fluids with…