Henry’s law

Henry’s law states that at a constant temperature, the amount of gas that dissolves in a liquid is directly proportional to the partial pressure of that gas in equilibrium with the liquid. In other words, the solubility of a gas in a liquid is directly proportional to the pressure of that gas above the liquid.…

Seven crystal systems (cell parameters a, b, c, α, β, γ)

The seven crystal systems and their corresponding cell parameters are: In each crystal system, the cell parameters describe the dimensions and angles of the unit cell, which is the basic repeating unit of a crystal lattice. The dimensions are given by the three lengths a, b, and c, and the angles between them, α, β,…

Classification of solids

Solids can be classified into various types based on different criteria. Here are some common ways of classifying solids: a. Crystalline solids: These are solids in which the atoms/molecules are arranged in a regular and repeating pattern. Examples include diamonds, salt, and metals. b. Amorphous solids: These are solids in which the atoms/molecules are arranged…

Activity and selectivity of solid catalysts

Solid catalysts are materials that accelerate chemical reactions by providing a surface for reactant molecules to adsorb onto and react. The activity of a solid catalyst is a measure of how effectively it can promote a particular chemical reaction, while selectivity refers to its ability to selectively form a desired product and minimize the formation…

Temperature dependence of rate constant (Arrhenius equation and activation energy)

The temperature dependence of a chemical reaction’s rate constant can be described by the Arrhenius equation, which relates the rate constant to the temperature and the activation energy of the reaction: k = A * exp(-Ea/RT) where k is the rate constant, A is the pre-exponential factor or frequency factor, Ea is the activation energy,…

Differential and integrated rate expressions for zero and first order reactions

The rate of a chemical reaction is the change in the concentration of reactants or products per unit time. The rate law for a chemical reaction describes how the rate of the reaction depends on the concentrations of the reactants. There are different rate laws for different types of reactions, but two common types are…

Rate constant

The rate constant, also known as the reaction rate constant, is a proportionality constant that relates the rate of a chemical reaction to the concentrations of the reactants. It is typically denoted by the symbol k and has units of inverse time (e.g., s^-1, min^-1, etc.). The value of the rate constant depends on a…

Rate law

A rate law is an equation that describes how the rate of a chemical reaction depends on the concentrations of the reactants. It is also known as the rate equation or the rate expression. The general form of a rate law is: Rate = k [A]^m [B]^n Where: The orders m and n are usually…

Order and molecularity of reactions

In chemistry, the order of a reaction refers to the exponent to which the concentration of a reactant is raised in the rate equation of a reaction. The molecularity of a reaction refers to the number of molecules, ions or atoms that participate in the reaction’s rate-determining step. For example, consider the reaction: A +…

Rates of chemical reactions

Chemical reactions can occur at different rates, depending on several factors such as temperature, concentration of reactants, the presence of a catalyst, surface area of reactants, and the nature of the reactants. The rate of a chemical reaction is defined as the change in concentration of reactants or products per unit time. The rate of…